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A fossil found in an archaeological dig was found to contain 20% of the original amount of 14C. I do not get the $-0.693$ value, but perhaps my answer will help anyway.

If we assume Carbon-14 decays continuously, then $$ C(t) = C_0e^, $$ where $C_0$ is the initial size of the sample. Since it takes 5,700 years for a sample to decay to half its size, we know $$ \frac C_0 = C_0e^, $$ which means $$ \frac = e^, $$ so the value of $C_0$ is irrelevant.

For radiocarbon dating to be possible, the material must once have been part of a living organism.

Thereafter, the concentration (fraction) of 14C declines at a fixed exponential rate due to the radioactive decay of 14C. ) Comparing the remaining 14C fraction of a sample to that expected from atmospheric 14C allows us to estimate the age of the sample.

As explained below, the radiocarbon date tells us when the organism was alive (not when the material was used).

This fact should always be remembered when using radiocarbon dates.

When an organism dies, the amount of 12C present remains unchanged, but the 14C decays at a rate proportional to the amount present with a half-life of approximately 5700 years.

This change in the amount of 14C relative to the amount of 12C makes it possible to estimate the time at which the organism lived.




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